PBDE

definition

Last update: 29/05/2026

Polybrominated diphenyl ethers (PBDEs) are a class of brominated flame retardants (BFRs) [3], organobrominated compounds with a basic structure of two phenyl rings linked by an oxygen atom (diphenyl ether) [1]. These compounds have been added to commercial and consumer products, such as textiles, carpets, building materials, and electronic devices, to reduce their flammability, typically at concentrations of 5% to 30% by weight [1].
Fig.1 Generic structure of Polybrominated diphenyl ethers (PBDEs) [2]
There are 209 possible PBDE congeners, differentiated by the number (from 1 to 10) and position of bromine atoms in the phenyl rings [1]. They are classified into 10 homologous groups, from mono-BDE (1 bromine) to deca-BDE (10 bromines) [2]. The most widely used industrially were Penta-BDE, Octa-BDE, and Deca-BDE.

They are persistent organic pollutants (POPs), resistant to degradation and capable of bioaccumulating in fatty tissues of living beings. They have been detected in even remote ecosystems (such as the Arctic) and in the human food chain, including breast milk [10].

Studies have linked their exposure to endocrine disruption (interference with thyroid hormones), neurological damage in children, and possible carcinogenic effects in animal models. Human exposure occurs mainly through ingestion of house dust, contaminated food (fatty fish, meat), and contact with electronic products.

PBDEs are banned in much of the world under the Stockholm Convention (Penta-BDE and Octa-BDE since 2009; Deca-BDE restricted since 2017) [12]. The European Union included them in its list of priority substances (REACH Regulation) and in the RoHS Directive for electronics.

They have now been replaced by halogen-free flame retardants, such as phosphorus compounds, metal hydroxides, or intumescent materials.

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